Eliminating Nanocrystal Surface Light Loss and Ion Migration to Achieve Bright Mixed-Halide Blue Perovskite LEDs.

Blue light-emittin g diodes (LEDs) are important components for perovskite electroluminescence applications, which still suffer from insufficient luminescence efficiency and poor stability. In Cl/Br mixed perovskite NCs, surficial defects cause severe light failure and ion migration, the in-depth mechanism of which is also not clear. To gain insights into these issues, we employ the ligand post-addition approach for mixed Cl/Br NCs by using octylammonium hydrobromide (OctBr) ligands, which effectively decrease surficial light loss and block ion migration pathways. The passivated CsPbCl 1.5 Br 1.5 NCs exhibit exceptional blue emission with 95% PLQY, and the electroluminescence spectra of LEDs are located at the initial positions at the initial states. The treated NC blue devices show a negligible color shift as the voltage increases, which proves that electric-field-driven ion migration is drastically suppressed. In addition, OctBr-treated CsPbCl 1.5 Br 1.5 and CsPbClBr 2 NC LEDs show high external quantum efficiencies of 2.42 and 3.05% for emission peaks at 456 and 480 nm, respectively. Our work identified the nature of NC surface defects and provided a surficial modification approach to develop high-performance and color-stable blue mixed-halide perovskite LEDs.