A metal-free hydroxyl functionalized quaternary phosphine type ionic liquid polymer for cycloaddition of CO 2 and epoxides.

Quaternary phosphine type hypercrosslinked polymer catalysts were successfully prepared using the Friedel-Crafts alkylation reactions, which benefit from the synergistic effects between the Brønsted acidity of the hydroxyl group and nucleophilicity of the Br - group as well as the CO 2 capture of the ionic liquids. The as-obtained metal-free catalysts facilitate the cycloaddition and synthesis of high value-added fine chemicals.