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Iron pentacarbonyl ligands on silver scorpionates.

Guocang WangAnurag Noonikara-PoyilIsrael FernándezH V Rasika Dias
Published in: Chemical communications (Cambridge, England) (2022)
Fluorinated tris(pyrazolyl)borate supporting ligands enable the stabilization of silver(I) bonded to a neutral, organometallic Fe(CO) 5 ligand. The Ag-Fe interaction in these molecules is mainly electrostatic in nature, but σ-donor and backbonding contributions between the two metal fragments also play notable roles, which can be modulated by the scorpionate substituents.
Keyphrases
  • gold nanoparticles
  • visible light
  • silver nanoparticles
  • metal organic framework
  • quantum dots
  • aqueous solution
  • molecular dynamics simulations
  • iron deficiency