Visible-light-induced ATRP under high-pressure: synthesis of ultra-high-molecular-weight polymers.

Roksana Bernat Grzegorz Szczepaniak Kamil KaminskiMarian PaluchKrzysztof Matyjaszewski Paulina Maksym

Published in: Chemical communications (Cambridge, England) (2023)

In this study, a high-pressure-assisted photoinduced atom transfer radical polymerization ( p ≤ 250 MPa) enabled the synthesis of ultra-high-molecular-weight polymers (UHMWPs) of up to 9 350 000 and low/moderate dispersity (1.10 < Đ < 1.46) in a co-solvent system (water/DMSO), without reaction mixture deoxygenation.

Keyphrases

visible light
electron transfer
high resolution
high glucose
diabetic rats
molecular dynamics
high intensity
drug induced
mass spectrometry