CIDNP as a tool to unveil the reaction mechanism: interaction of mixed phosphonium-iodonium ylide with p -methoxyphenylacetylene.

Irina I LevinaValery F TarasovTatyana A PodruginaTatiana D Nekipelova

Published in: RSC advances (2019)

In situ acquisition of the reaction between benzoyl phosphonium-iodonium ylide and p -methoxyphenylacetylene in an NMR spectrometer reveals the CIDNP effect in 31 P and 1 H NMR spectra of major products, substituted furan (emission) and phosphonium salt (enhanced absorption). The mechanism of products formation via radical pairs is discussed.

Keyphrases

ionic liquid
high resolution
solid state
magnetic resonance
molecular docking
mass spectrometry
density functional theory