Facile Exfoliation of Few-Layer Sn-Based Nanosheets for Self-Powered Photo-Electrochemical and All-Optical Modulation Applications.

Few-layer tin (Sn)-based nanosheets (NSs) with a thickness of ≈2.5 nm are successfully prepared using a modified liquid phase exfoliation (LPE) method. Here the first exploration of photo-electrochemical (PEC) and nonlinear properties of Sn NSs is presented. The results demonstrate that the PEC properties are tunable under different experimental conditions. Additionally, Sn NSs are shown to exhibit a unique self-powered PEC performance, maintaining a good long-term stability for up to 1 month. Using electron spin resonance, active species, such as hydroxyl radicals (·OH), superoxide radicals (·O 2 - ), and holes (h + ), are detected during operations, providing a deeper understanding of the working mechanism. Furthermore, measurements of nonlinear response reveal that Sn NSs can be effective for all-optical modulation, as it enables the realization of all-optical switching through excitation spatial cross-phase modulation (SXPM). These findings present new research insights and potential applications of Sn NSs in optoelectronics.