Ti4(embonate)6 Cage-Ligand Strategy on the Construction of Metal-Organic Frameworks with High Stability and Gas Sorption Properties.

Yan-Ping HeGuang-Hui ChenLv-Bing YuanLei Zhang Jian Zhang

Published in: Inorganic chemistry (2020)

Herein we report an efficient strategy to construct cage-based metal-organic frameworks (MOFs) via the assembly of Ti4L6 (L = embonate) cages and N-contained ligands with Mn2+ and Zn2+ ions, respectively, and two Ti4L6-cage-based MOFs (PTC-219 and PTC-220) with high stability and gas sorption properties have been generated through two-step reactions, respectively.

Keyphrases

metal organic framework
room temperature
heavy metals
sewage sludge
carbon dioxide
quantum dots
risk assessment
organic matter