Thiol-Stabilized Gold Nanoparticles: New Ways To Displace Thiol Layers Using Yttrium or Lanthanide Chlorides.
Julie P VanegasJuan C ScaianoAnabel E LanternaPublished in: Langmuir : the ACS journal of surfaces and colloids (2017)
We use the aurophilic interactions shown by lanthanides to overcome the sulfur-gold interaction. UV-vis and X-ray photoelectron spectroscopy confirm that yttrium or lanthanide chlorides easily displace sulfur ligands from the surface of thiol-stabilized gold nanoparticles.