Proton-Activated Amorphous Room-Temperature Phosphorescence for Humidity Sensing and High-Level Data Encryption.

Supramolecular co-assembling terpyridine-derivatives with nanoclay (LP) are exploited to acquire efficient amorphous room-temperature phosphorescence (RTP). Experimental and theoretical investigations reveal that this co-assembly not only brings about a configuration transformation from the trans-trans (a) to the cis-trans (a'') form via the protonating process, significantly narrowing the singlet-triplet energy gap, thereby effectively facilitating the single-triplet ISC processes, but also well protects the triplet state and suppresses the nonradiative transitions via restricting molecular rotation and vibration by the hydrogen-bond interactions between them. Additionally, the flexible and transparent films, through co-assembling 1@LP (or 2@LP) with polyvinyl alcohol (PVA), also display excellent phosphorescence performance. Owing to their distinctive RTP performances, the RH sensing and high-level data encryption are achieved.