In situ growth of Prussian blue analogue-derived Fe-doped NiS on Ni(OH) 2 for efficient hydrogen evolution reaction.

The energy industry is placing more and more emphasis on the need for effective and affordable electrocatalysts for hydrogen evolution reactions (HER). In this work, an iron-doped NiS/Ni(OH) 2 /CC composite material was synthesized by simple hydrothermal sulfurization processes of bimetallic Prussian blue analogue (PBAs) precursors grown in situ on three-dimensional (3D) Ni(OH) 2 nanosheets. The overpotential can be 103 mV to attain current densities of 10 mA cm -2 . The excellent catalytic activity of Fe-NiS/Ni(OH) 2 /CC is because of the unique 3D structure and the uniform doping of iron caused by the in situ growth of PBA, as well as the high conductivity of the self-supported electrode carbon cloth.