A reduced polyoxometalate-encapsulated organo cobalt modified phosphate framework for improving photocatalytic reduction of CO 2 .

A reduced polyoxometalate-based organo-metallophosphate (MOPO) framework formulated as [Co 4 (PO 4 )(C 7 H 8 N 4 ) 6 ](PWVI10WV2O 40 ) (Co-PO4-PW12) with an ultra-high CO production rate of 13 676 μmol g -1 h -1 has been presented through photocatalytic CO 2 reduction investigations.