MaDDOSY (Mass Determination Diffusion Ordered Spectroscopy) using an 80 MHz Bench Top NMR for the Rapid Determination of Polymer, Macromolecular Molecular Weight.
Owen TooleyWilliam PointerRowan RadmallMia HallValentin BeyerKieran StakemThomas SwiftJames TownTanja JunkersPaul WilsonDaniel LesterDavid M HaddletonPublished in: Macromolecular rapid communications (2024)
Measurement of molecular weight is an integral part of macromolecular and polymer characterization which usually has limitations. Herein, we present the use of a bench-top 80 MHz NMR spectrometer for diffusion-ordered spectroscopy as a practical and rapid approach for the determination of molecular weight/size using a novel solvent and polymer-independent universal calibration. This article is protected by copyright. All rights reserved.