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Synthesis of Tetracyclic C 2 -Symmetric Ketiminium Salts and Evaluation as Catalysts for Epoxidation.

G Sudhakar ReddyE J Corey
Published in: Organic letters (2023)
Short synthetic routes to the nonplanar tetracyclic ketiminium salt A and two close analogs are described. These are helical nonplanar structures as shown by X-ray crystallography.
Keyphrases
  • high resolution
  • highly efficient
  • molecular docking
  • ionic liquid
  • transition metal
  • magnetic resonance
  • computed tomography
  • molecular dynamics simulations