Modulating the metal center in MIL-101 for the piezoelectric catalytic synthesis of hydrogen peroxide.

Yatai LiZhi LiXuecong LinHao LvMingshan Zhu

Published in: Chemical communications (Cambridge, England) (2023)

Modulation of metal centers is a promising strategy to boost catalytic performance. Two structurally identical MOFs with different metal centers, namely MIL-101(Cr) and MIL-101(Fe), were synthesized. MIL-101(Cr) exhibits superior H 2 O 2 yield due to Cr's electron-donating ability. This work helps in developing the rational design and optimization of MOF catalysts for catalytic reactions.

Keyphrases

metal organic framework
hydrogen peroxide
nitric oxide
crystal structure
signaling pathway
solid phase extraction
high resolution