A sustainable C-H functionalization of indoles, pyrroles and furans under a blue LED with iodonium ylides.

Pyrrole and indole derivatives are functionalized via a green initiative with the dimethyl malonate derived phenyl iodonium ylide 4a in the presence of a blue LED via C-H functionalization of the respective heterocycles in methanol to generate the desired compounds 5-7 in moderate to good yields. Control experiments provide insight into the probable reaction mechanism. Finally, the strategy is successfully applied in the generation of azepino[4,5-b]indole 12a/b.