A novel Cu(I)-based coordination polymer for efficient photocatalytic oxidation of C(sp 3 )-H bonds.

Jiangtao DengHuilin HuangZhentao LiXu Jing Chun-Ying Duan

Published in: Dalton transactions (Cambridge, England : 2003) (2024)

A novel coordination polymer CuCl-Pyhc was successfully synthesized, which can catalyze efficient and selective oxidation of C(sp 3 )-H bonds under mild conditions, exhibiting exceptional stability and remarkable recyclability. Furthermore, CuCl-Pyhc can mimic natural monooxygenases and activate oxygen into singlet oxygen ( 1 O 2 ).

Keyphrases

visible light
hydrogen peroxide
electron transfer
transition metal
metal organic framework