Water-based synthesis and characterisation of a new Zr-MOF with a unique inorganic building unit.
S WaitschatH ReinschNorbert StockPublished in: Chemical communications (Cambridge, England) (2018)
A new, microporous Zr-MOF was obtained using 2,5-pyrazinedicarboxylic acid (H2PzDC). The linker leads to the formation of a new 1D inorganic building unit composed of μ-OH bridged {Zr6O4(OH4)} clusters which are arranged in a hexagonal array and connected by the PzDC2- ions. The structure was determined from powder X-ray diffraction data.
Keyphrases
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