Imaging of Al/Fe ratios in synthetic Al-goethite revealed by nanoscale secondary ion mass spectrometry.
Lydia PohlAngelika KölblFlorian WernerCarsten W MuellerCarmen HoeschenWerner HäuslerIngrid Kögel-KnabnerPublished in: Rapid communications in mass spectrometry : RCM (2018)
NanoSIMS measurements confirmed the capacity to produce images, which indicated the uniform increase in Al-concentrations in goethite. Using a combination of statistical analysis with information from complementary spectroscopic techniques (XRD, FTIR and Mössbauer spectroscopy) we were further able to reveal spots with lower Al/Fe ratios as hematite.