Oxidation Potential Tunable Organic Molecules and Their Catalytic Application to Aerobic Dehydrogenation of Tetrahydroquinolines.

Dahyeon JungSeol Heui JangTaeeun Yim Jinho Kim

Published in: Organic letters (2018)

In this work, oxidation potential tunable organic molecules, alkyl 2-phenyl hydrazocarboxylates, were disclosed. The exquisite tuning of their oxidation potentials facilitated a catalytic dehydrogenation of 1,2,3,4-tetrahydroquinolines in the presence of Mn(Pc) and O2.

Keyphrases

hydrogen peroxide
visible light
electron transfer
energy transfer
risk assessment
nitric oxide
room temperature
transition metal