Formal Enone α-Arylation via I(III)-Mediated Aryl Migration/Elimination.

Bruna S Martins Daniel Kaiser Adriano BauerIrmgard TiefenbrunnerNuno Maulide

Published in: Organic letters (2021)

A formal enone α-arylation is described. This metal-free transformation relies on the I(III)-mediated skeletal reorganization of silyl enol ethers and features mild conditions, good yields, and high stereoselectivities for β-substituted enones.

Keyphrases

molecular docking