Highly Switchable Adhesion of N-Doped Graphene Interfaces for Robust Micromanipulation.

We demonstrated an N-doped graphene interface with highly switchable adhesion and robust micromanipulation capability triggered by external electric signals. Upon applying a small dc or ac electrical bias, this nanotextured surface can collect environmental moisture to form a large number of water bridges between the graphene and target surface, which lead to a drastic change in adhesive force. Turning on and off the electrical bias can control this graphene interface as a robust micro/nanomanipulator to pick up and drop off various micro/nano-objects for precise assembling. Molecular dynamics simulation reveals that the electrically induced electric double layer and ordered icelike structures at the graphene-water interface strengthen the water bridges and consequently enhance force switchability. In addition to the micro-/nanomanipulation, this switchable adhesion may have many technical implications such as climbing robots, sensors, microfluidic devices, and advanced drug delivery.