High-Performance Ag-Cu Nanoalloy Catalyst for the Selective Catalytic Oxidation of Ammonia.

High-performance Ag-Cu alloy nanoparticles (NPs) were successfully synthesized by a solventless mix-bake-wash method and tested for NH3-SCO. The prepared Ag2Cu1 catalyst with a perfect Ag-Cu alloy structure exhibited better T100 (200 °C, the temperature at which 100% NH3 conversion was obtained), higher reaction rates, and lower Ea compared to that with ordinary bimetallic Ag-Cu (AgCuOx). The characterization data revealed much smaller Ag-Cu alloy nanoparticles of the Ag2Cu1 catalyst and more Ag/Cu metallic species on the surface, which can increase the amount of chemisorbed surface oxygen (Oβ) and enhance NH3 adsorption and activation in the low-temperature range, therefore leading to a much higher NH3-SCO activity. Kinetic studies and density functional theory calculations indicated that Cu decoration at Ag by Ag-Cu alloying could enhance the adsorption/activation of NH3 and O2. It has been found that O2 was more easily transformed from the adsorption state to the transition state than NH3, which enhanced the performance of NH3 oxidation. In addition, the Ag2Cu1 catalyst exhibited excellent durability because of the stabilization of Ag sites by the Ag-Cu alloy structure.