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Cerium-photocatalyzed aerobic oxidation of benzylic alcohols to aldehydes and ketones.

Girish Suresh YedaseSumit KumarJessica StahlBurkhard KönigVeera Reddy Yatham
Published in: Beilstein journal of organic chemistry (2021)
We have developed a cerium-photocatalyzed aerobic oxidation of primary and secondary benzylic alcohols to aldehydes and ketones using inexpensive CeCl3·7H2O as photocatalyst and air oxygen as the terminal oxidant.
Keyphrases
  • visible light
  • oxide nanoparticles
  • hydrogen peroxide
  • high intensity
  • electron transfer
  • highly efficient