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Non-threaded and rotaxane-type threaded wheel-axle assemblies consisting of dinickel(II) metallomacrocycle and dibenzylammonium axle.

Yoko SakataSeiya KobayashiMisato YamamotoKatsuya DokenMayu KamezawaSachiko YamakiShigehisa Akine
Published in: Communications chemistry (2024)
Rotaxanes are typically prepared using covalent bonds to trap a wheel component onto an axle molecule, and rotaxane-type wheel-axle assembly using only noncovalent interactions has been far less explored. Here we show that a dinickel(II) metallomacrocycle forms two different types of wheel-axle assemblies with a dibenzylammonium axle molecule based only on noncovalent interactions. The non-threaded assembly was obtained by introduction of Ni 2+ into the macrocycle before the complexation with the axle molecule (metal-first method). The non-threaded assembly was in rapid equilibrium with each of the components in solution. The threaded assembly was obtained by introduction of Ni 2+ after the formation of a pseudorotaxane from the non-metalated wheel and the axle molecule (axle-first method). The threaded assembly was not in equilibrium with the dissociated species even though it was maintained only by noncovalent interactions. Thus, formation of one of the non-threaded and threaded wheel-axle assemblies over the other is governed by the assembly pathway.
Keyphrases
  • transition metal