Facile assembly of bifunctional, magnetically retrievable mesoporous silica for enantioselective cascade reactions.
Zhongrui ZhaoFengwei ChangTao WangLijian WangLingbo ZhaoCheng PengGuohua LiuPublished in: Chemical communications (Cambridge, England) (2019)
An integrated immobilization to encapsulate the Pd/C-coated magnetic nanoparticles within the chiral Ru/diamine-functionalized silica shell for the construction of a bifunctional magnetic catalyst is developed. This catalyst realizes a synergistic Suzuki cross-coupling/asymmetric transfer hydrogenation and a successive reduction/asymmetric transfer hydrogenation for the preparation of chiral aromatic alcohols.
Keyphrases
- magnetic nanoparticles
- highly efficient
- metal organic framework
- molecularly imprinted
- ionic liquid
- reduced graphene oxide
- capillary electrophoresis
- room temperature
- quantum dots
- visible light
- solid state
- solid phase extraction
- gold nanoparticles
- inferior vena cava
- mass spectrometry
- cancer therapy
- carbon dioxide
- drug delivery
- liquid chromatography