The Impact of Oxygen Surface Coverage and Carbidic Carbon on the Activity and Selectivity of Two-Dimensional Molybdenum Carbide (2D-Mo 2 C) in Fischer-Tropsch Synthesis.

Transformations of oxygenates (CO 2 , CO, H 2 O, etc.) via Mo 2 C-based catalysts are facilitated by the high oxophilicity of the material; however, this can lead to the formation of oxycarbides and complicate the identification of the (most) active catalyst state and active sites. In this context, the two-dimensional (2D) MXene molybdenum carbide Mo 2 C T x ( T x are passivating surface groups) contains only surface Mo sites and is therefore a highly suitable model catalyst for structure-activity studies. Here, we report that the catalytic activity of Mo 2 C T x in Fischer-Tropsch (FT) synthesis increases with a decreasing coverage of surface passivating groups (mostly O*). The in situ removal of T x species and its consequence on CO conversion is highlighted by the observation of a very pronounced activation of Mo 2 C T x (pretreated in H 2 at 400 °C) under FT conditions. This activation process is ascribed to the in situ reductive defunctionalization of T x groups reaching a catalyst state that is close to 2D-Mo 2 C (i.e., a material containing no passivating surface groups). Under steady-state FT conditions, 2D-Mo 2 C yields higher hydrocarbons (C 5+ alkanes) with 55% selectivity. Alkanes up to the kerosine range form, with value of α = 0.87, which is ca. twice higher than the α value reported for 3D-Mo 2 C catalysts. The steady-state productivity of 2D-Mo 2 C to C 5+ hydrocarbons is ca. 2 orders of magnitude higher relative to a reference β-Μo 2 C catalyst that shows no in situ activation under identical FT conditions. The passivating T x groups of Mo 2 C T x can be reductively defunctionalized also by using a higher H 2 pretreatment temperature of 500 °C. Yet, this approach leads to a removal of carbidic carbon (as methane), resulting in a 2D-Mo 2 C 1- x catalyst that converts CO to CH 4 with 61% selectivity in preference to C 5+ hydrocarbons that are formed with only 2% selectivity. Density functional theory (DFT) results attribute the observed selectivity of 2D-Mo 2 C to C 5+ alkanes to a higher energy barrier for the hydrogenation of surface alkyl species relative to the energy barriers for C-C coupling. The removal of O* is the rate-determining step in the FT reaction over 2D-Mo 2 C, and O* is favorably removed in the form of CO 2 relative to H 2 O, consistent with the observation of a high CO 2 selectivity (ca. 50%). The absence of other carbon oxygenates is explained by the energetic favoring of the direct over the hydrogen-assisted dissociative adsorption of CO.