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A facile route for the recovery of the ligand of zeolitic imidazolate framework ZIF-94/SIM-1.

Victor Berned-SamatánLidia Martínez-IzquierdoElisa AbásCarlos TéllezJoaquín Coronas
Published in: Chemical communications (Cambridge, England) (2022)
A facile route for the recycling of the organic ligand from ZIF-94/SIM-1 is reported with a recovery yield of 92.5 ± 2.8%. The recycled ligand was used for a new ZIF-94 synthesis compared to the one using fresh ligand. ZIF-94 was embedded in Pebax® 1657 mixed matrix membranes for gas separation of CO 2 /N 2 and CO 2 /CH 4 mixtures.
Keyphrases
  • reduced graphene oxide
  • gold nanoparticles
  • liquid chromatography
  • metal organic framework
  • visible light