Algal Biochar-Metal Nanocomposite Particles Tailor the Hydration Kinetics and Compressive Strength of Portland Cement Paste.

Biochar can improve the mechanical properties of portland cement paste and concrete. In this work, we produced algal biochar-zinc (biochar-Zn) and algal biochar-calcium (biochar-Ca) nanocomposite particles and studied their effect on the hydration kinetics and compressive strength of cement paste. Results show that 3 wt % biochar-Zn delayed peak heat evolution during cement hydration from 8.3 to 10.0 h, while 3 wt % addition of biochar-Ca induced a minor acceleration of peak heat from 8.3 to 8.2 h. Both biochar-Zn and biochar-Ca nanocomposite particles increased the compressive strength of cement paste at 28 days by 22.6 and 17.0%, respectively. Data substantiate that retardation or minor acceleration of the reaction kinetics was due exclusively to the presence of Zn and Ca phases, respectively, while the enhanced strength was attributed to a nucleation effect induced by such phases and the internal curing effect of biochar.