Synthesis and crystal structure of a penta-copper(II) 12-metallacrown-4: cis-di-aqua-tetra-kis-(di-methyl-formamide-κO)manganese(II) tetra-kis-(μ3-N,2-dioxido-benzene-1-carboximidate)penta-copper(II) di-methyl-formamide monosolvate.

The title compound, [Mn(C3H7NO)4(H2O)2][Cu5(C7H4NO3)4]·C3H7NO or cis-[Mn(H2O)2(DMF)4]{Cu[12-MCCu(II)N(shi)-4]}·DMF, where MC is metallacrown, shi3- is salicyl-hydroximate, and DMF is N,N-di-methyl-formamide, crystallizes in the monoclinic space group P21/n. Two crystallographically independent metallacrown anions are present in the structure, and both anions exhibit minor main mol-ecule disorder by an approximate (non-crystallographic) 180° rotation with occupancy ratios of 0.9010 (9) to 0.0990 (9) for one anion and 0.9497 (8) to 0.0503 (8) for the other. Each penta-copper(II) metallacrown contains four CuII ions in the MC ring and a CuII ion captured in the central cavity. Each CuII ion is four-coordinate with a square-planar geometry. The anionic {Cu[12-MCCu(II)N(shi)-4]}2- is charged-balanced by the presence of a cis-[Mn(H2O)2(DMF)4]2+ cation located in the lattice. In addition, the octa-hedral MnII counter-cation is hydrogen bonded to both MC anions via the coordinated water mol-ecules of the MnII ion. The water mol-ecules form hydrogen bonds with the phenolate and carbonyl oxygen atoms of the shi3- ligands of the MCs.