Optimizing Coaxial Sonic Spray Geometry for Generating Water Microdroplets.

Sonic spray creates a stream of neutral and charged microdroplets without application of voltage, heating, laser irradiation, or corona discharge. The solvent of interest flows through an inner capillary (usually constructed of fused silica) that is surrounded by an outer stainless-steel tube through which a nebulizing gas flows under pressure. This technique has been widely used as the interface in mass spectrometric studies for chemical analysis and for understanding microdroplet chemistry. We have used light scattering to characterize the size distribution and density for water microdroplets as a function of several parameters, such as water quality, water flow rate, nebulizing gas pressure, and sonic sprayer geometry. We find that the size distribution of the microdroplets, which is critical to many applications, depends most sensitively on the distance between the inner and outer capillary outlets and the gas flow pressure. The best performance as measured by the smallness of the microdroplet diameters is obtained when the gas flow pressure is the highest and there is no separation distance, d , between the two capillary outlets. In addition, at d = 0 mm, the microdroplet diameter distribution is nearly independent of the water flow rate, indicating that studies under these conditions can be scaled up.