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Modulation of single-chain magnet behaviour in a heterometallic Fe 2 Co cyanide-bridged 2D sheet.

Ranjan KharelJyoti YadavSanjit Konar
Published in: Chemical communications (Cambridge, England) (2023)
A cyanide-bridged Fe 2 Co 2D sheet exhibiting electron transfer coupled spin transition (ETCST) with co-existence of magnetic ordering below 50 K is reported. The complex exhibits single-chain magnet behaviour where the uncoordinated water molecules act as an exchange-breaking impurity by allowing only a fraction of the molecule to undergo a spin state change. The paramagnetic centres prevail throughout the chain on desolvation, thereby increasing the number of correlated units in the chain.
Keyphrases
  • electron transfer
  • room temperature
  • single molecule
  • fluorescent probe
  • mass spectrometry
  • molecularly imprinted
  • ionic liquid
  • liquid chromatography
  • simultaneous determination