Organo-Photoredox Catalyzed C(sp 3 )-H Bond Arylation of Aliphatic Amides.

A C(sp 3 )-H bond arylation of aliphatic amides has been achieved via organophotoredox catalysis. The reaction could be realized at room temperature with visible light source and metal-free catalyst. Quinuclidine is employed as an efficient HAT reagent and a range of aliphatic amides is employed as both substrate and solvent in the reaction. This photocatalyzed transformation provides a convenient protocol to afford a board range of N-benzyl amides.