Inserting Amide into NOTT-101 to Sharply Enhance Volumetric and Gravimetric Methane Storage Working Capacity.
Mingxing ZhangCong ChenZhe ShiKunlin HuangWensheng FuWei ZhouPublished in: Inorganic chemistry (2019)
Amide-functionalized NJU-Bai45 exhibits high volumetric and gravimetric CH4 working capacities of 190 cm3 cm-3 and 298 cm3 g-1 (from 5.8 to 65 bar), higher than that of the similar NJU-Bai43 (187 cm3 cm-3 and 292 cm3 g-1). This finding indicates that nitrogen-functionalized aromatic ring may not always play a positive role in amide-MOF for CH4 storage.