Superabsorption in an organic microcavity: Toward a quantum battery.
James Q QuachKirsty E McGheeLucia GanzerDominic M RouseBrendon W LovettErik Manuel GaugerJonathan KeelingGiulio CerulloDavid G LidzeyTersilla VirgiliPublished in: Science advances (2022)
The rate at which matter emits or absorbs light can be modified by its environment, as markedly exemplified by the widely studied phenomenon of superradiance. The reverse process, superabsorption, is harder to demonstrate because of the challenges of probing ultrafast processes and has only been seen for small numbers of atoms. Its central idea—superextensive scaling of absorption, meaning larger systems absorb faster—is also the key idea underpinning quantum batteries. Here, we implement experimentally a paradigmatic model of a quantum battery, constructed of a microcavity enclosing a molecular dye. Ultrafast optical spectroscopy allows us to observe charging dynamics at femtosecond resolution to demonstrate superextensive charging rates and storage capacity, in agreement with our theoretical modeling. We find that decoherence plays an important role in stabilizing energy storage. Our work opens future opportunities for harnessing collective effects in light-matter coupling for nanoscale energy capture, storage, and transport technologies.
Keyphrases
- energy transfer
- solid state
- single molecule
- molecular dynamics
- high resolution
- atomic force microscopy
- quantum dots
- electron transfer
- monte carlo
- wastewater treatment
- machine learning
- big data
- room temperature
- high speed
- highly efficient
- mass spectrometry
- water soluble
- molecular dynamics simulations
- deep learning
- ionic liquid