A mixed-spin spin-crossover thiozolylimine [Fe4L6]8+ cage.
Li LiAlexander R CrazeOuti MustonenHikaru ZennoJacob J WhittakerShinya HayamiLeonard F LindoyChristopher E MarjoJack Kay CleggJanice Rae Aldrich-WrightFeng LiPublished in: Dalton transactions (Cambridge, England : 2003) (2019)
The self-assembly of a mixed-spin [Fe4L6]8+ tetrahedral cage is reported. The cage undergoes temperature induced spin-crossover with a 29 K hystereisis. Variable temperature X-ray photoelectron spectroscopy (VT-XPS), combined with SQUID data, allowed differentiation between the surface and bulk magnetic properties.
Keyphrases
- single molecule
- room temperature
- density functional theory
- transition metal
- high resolution
- open label
- electronic health record
- molecular dynamics
- double blind
- high glucose
- ionic liquid
- diabetic rats
- magnetic resonance imaging
- metal organic framework
- oxidative stress
- drug induced
- endothelial cells
- machine learning
- stress induced