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Comparison of Nanoscale Focused Ion Beam and Electrochemical Lithiation in β-Sn Microspheres.

Saya TakeuchiWilliam R McGeheeJennifer L SchaeferTruman M WilsonKevin A TwedtEddie H ChangChristopher L SolesVladimir P OleshkoJabez J McClelland
Published in: Journal of the Electrochemical Society (2016)
The development of Li focused ion beams (Li-FIB) enables controlled Li ion insertion into materials with nanoscale resolution. We take the first step toward establishing the relevance of the Li-FIB for studies of ion dynamics in electrochemically active materials by comparing FIB lithiation with conventional electrochemical lithiation of isolated β-Sn microspheres. Samples are characterized by cross-sectioning with Ga FIB and imaging via electron microscopy. The Li-FIB and electrochemical lithiated Sn exhibit similarities that suggest that the Li-FIB can be a powerful tool for exploring dynamical Li ion-material interactions at the nanoscale in a range of battery materials.
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