High nuclearity structurally - related Mn supertetrahedral T4 aggregates.

Katerina SkordiAntonis AnastassiadesAdeline D FournetRahul KumarMichael Schulze Wolfgang Wernsdorfer George Christou Vassilios Nastopoulos Spyros P Perlepes Constantina Papatriantafyllopoulou Anastasios J Tasiopoulos

Published in: Chemical communications (Cambridge, England) (2021)

The simultaneous employment of 1,3-propanediol and di-2-pyridyl ketone in Mn carboxylate chemistry has provided access to three new, structurally-related [Mn24] and [Mn23] clusters. They are based on nanosized supertetrahedal T4 Mn/O structural cores and exhibit slow relaxation of magnetization below 3.5 K.

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