Phosphanyl-substituted tin half-sandwich complexes.
Carsten MüllerJustin SchuBernd MorgensternMichael ZimmerMarc SchmidtmannAndré SchäferPublished in: RSC advances (2023)
Phosphanyl-substituted tin(ii) half sandwich complexes are reported. Due to the Lewis acidic tin center and Lewis basic phosphorous atom they form head-to-tail dimers. Their properties and reactivities were investigated both experimentally and theoretically. Furthermore, related transition metal complexes of these species are presented.