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Perovskite Quantum Dots Lasing in Double-Heterostructure through Energy Transfer.

Zihao ChuYang LiRiyu CongXinrui MaoYanping LiWanjin XuYunan GaoGuangzhao Ran
Published in: Nano letters (2024)
Planar double heterostructures were initially investigated and have been successfully applied in III-V semiconductor lasers due to their excellent roles in confining both the photons and carriers. Here, we design and fabricate a (PEA) 2 Cs n -1 Pb n X 3 n +1 (quasi-2D)/CsPbBr 3 QD/quasi-2D double-heterostructure sandwiched in a 3/2 λ DBR microcavity, and then demonstrate a single-mode pure-green lasing with a threshold of 53.7 μJ/cm 2 under nanosecond-pulsed optical pumping. The thresholds of these heterostructure devices decrease statistically by about 50% compared to the control group with no energy donor layers, PMMA/QD/PMMA in an identical microcavity. We show that there is efficient energy transfer from the barrier regions of the quasi-2D phases to the QD layer by transient absorption and luminescence lifetime spectra and that such energy transfer leads to marked threshold reduction. This work indicates that the double-heterostructure configurations should play a significant role in the future perovskite electrically pumped laser.
Keyphrases
  • energy transfer
  • quantum dots
  • room temperature
  • sensitive detection
  • high speed
  • heavy metals
  • high resolution
  • solar cells
  • high efficiency
  • current status
  • atomic force microscopy
  • mass spectrometry
  • single molecule