Solution-Processed Cu 2 S Nanostructures for Solar Hydrogen Production.

Cu 2 S is a promising solar energy conversion material due to its suitable optical properties, high elemental earth abundance, and nontoxicity. In addition to the challenge of multiple stable secondary phases, the short minority carrier diffusion length poses an obstacle to its practical application. This work addresses the issue by synthesizing nanostructured Cu 2 S thin films, which enables increased charge carrier collection. A simple solution-processing method involving the preparation of CuCl and CuCl 2 molecular inks in a thiol-amine solvent mixture followed by spin coating and low-temperature annealing was used to obtain phase-pure nanostructured (nanoplate and nanoparticle) Cu 2 S thin films. The photocathode based on the nanoplate Cu 2 S (FTO/Au/Cu 2 S/CdS/TiO 2 /RuO x ) reveals enhanced charge carrier collection and improved photoelectrochemical water-splitting performance compared to the photocathode based on the non-nanostructured Cu 2 S thin film reported previously. A photocurrent density of 3.0 mA cm -2 at -0.2 versus a reversible hydrogen electrode ( V RHE ) with only 100 nm thickness of a nanoplate Cu 2 S layer and an onset potential of 0.43 V RHE were obtained. This work provides a simple, cost-effective, and high-throughput method to prepare phase-pure nanostructured Cu 2 S thin films for scalable solar hydrogen production.