Irreversible photo-Fenton-like triggered agglomeration of ultra-small gold nanoparticles capped with crosslinkable materials.

A photo-Fenton-like process can promote the agglomeration and LSPR red-shifting of ultra-small gold nanoparticles by triggering a crosslink-degradation pathway that involves the surface coating, Fe(iii)-citrate and hydrogen peroxide. Applications may range from controlled photo-deposition of active materials to asynchronous sensing technologies to light-focused microfabrication.