Optical Nonlinearity of ZrS₂ and Applications in Fiber Laser.

Group VIB transition metal dichalcogenides (TMDs) have been successfully demonstrated as saturable absorbers (SAs) for pulsed fiber lasers. For the group comprising IVB TMDs, applications in this field remain unexplored. In this work, ZrS₂-based SA is prepared by depositing a ZrS₂ nanostructured film onto the side surface of a D-shaped fiber. The nonlinear optical properties of the prepared SA are investigated, which had a modulation depth of 3.3% and a saturable intensity of 13.26 MW/cm². In a pump power range of 144⁻479 mW, the Er-doped fiber (EDF) laser with ZrS₂ can operate in the dual-wavelength Q-switching state. The pulse duration declined from 10.0 μs down to 2.3 μs. The single pulse energy reached 53.0 nJ. The usage of ZrS₂ as a SA for pulse generation in fiber lasers is presented for the first time. Compared to the experimental results of dual-wavelength Q-switched fiber lasers with two-dimensional (2D) materials, our laser performance was better. Our work indicates that the group comprising IVB TMD ZrS₂ has bright prospects for nonlinear optical applications.