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A Flexible Cu-MOF as Crystalline Sponge for Guests Determination.

Qian-Feng QiuCheng-Xia ChenZhang-Wen WeiChen-Chen CaoNeng-Xiu ZhuHai-Ping WangDawei WangJi-Jun JiangCheng-Yong Su
Published in: Inorganic chemistry (2018)
A trifluoromethyl functionalized linker and Cu-O chain composed MOF, LIFM-100, was used as "crystalline sponge" to determine eight hardly crystallized liquids' configurations based on its flexibility conformation, suitable pore size, electron-rich channel environment, and low symmetric space group. The H bond interactions between host-guest and guest-guest were well analyzed.
Keyphrases
  • metal organic framework
  • room temperature
  • water soluble
  • molecularly imprinted
  • quantum dots
  • aqueous solution
  • molecular dynamics simulations
  • mass spectrometry
  • ionic liquid
  • tandem mass spectrometry