Electrochemical Detection of 4-Nitrophenol Using a Novel SrTiO 3 /Ag/rGO Composite.

In this study, an eco-friendly strategy was used to prepare a novel SrTiO 3 /Ag/rGO composite. A SrTiO 3 /Ag/rGO composite-modified screen-printed carbon electrode (SPCE) was applied for the electrochemical detection of 4-nitrophenol. A simple ultrasonic method with an ultrasonic frequency of 20 kHz was used for the synthesis of SrTiO 3 /Ag/rGO composite material. The obtained SrTiO 3 /Ag/rGO composite was characterized by X-ray diffraction, Fourier transform infrared, Raman spectroscopy, field emission electron microscopy, and UV-visible spectroscopy. Electrochemical impedance spectroscopy was used to determine the electrical conductivity of the SrTiO 3 /Ag/rGO composite. The electrochemical properties of the modified electrode were studied using cyclic voltammetry as well as linear sweep voltammetry techniques. In comparison to SrTiO 3 /SPCE, SrTiO 3 /Ag/SPCE, and SrTiO 3 /rGO/SPCE electrodes, SrTiO 3 /Ag/rGO/SPCE demonstrates a considerable increase in 4-nitrophenol redox peak current. At optimum conditions, a large linear response range of 0.1-1000 M, with a relatively low limit of detection (0.03 M), outperforms the previously published modified electrode for 4-nitrophenol. Moreover, the SrTiO 3 /Ag/rGO/SPCE electrode-based 4-nitrophenol sensor is distinguished by good selectivity, high stability, and repeatability. Furthermore, SrTiO 3 /Ag/rGO/SPCE contributed to the detection of 4-nitrophenol in river water and drinking water with the recovery range from 97.5 to 98.7%. The experimental finding was supported by density functional theory calculation.