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Mn(III)-Mediated Cascade Cyclization of 3-Isocyano-[1,1'-biphenyl]-2-carbonitrile with Arylboronic Acid: Construction of Pyrrolopyridine Derivatives.

Pei XuYi-Ming ZhuFei WangShun-Yi WangShun-Jun Ji
Published in: Organic letters (2019)
A Mn(III) mediated cascade cyclization of new designed multifunctionalized 3-isocyano-[1,1'-biphenyl]-2-carbonitrile with arylboronic acid to construct pyrrolopyridine derivatives is developed. A series of pyrroloporidine compounds have been constructed through the formation of two new C-C bonds and one C-N bond via a radical pathway.
Keyphrases
  • transition metal
  • room temperature
  • wastewater treatment
  • structure activity relationship
  • metal organic framework
  • high density