Supramolecular Electronic Interactions in Porphyrin-SWCNT Hybrids through Amidinium-Carboxylate Connectivity.

Laura Rodríguez-PérezSonia VelaCarmen AtienzaNazario Martin

Published in: Organic letters (2017)

New supramolecular (metal)porphyrin/SWCNT hybrids have been synthesized through a combination of hydrogen bond and electrostatic interactions. Our experimental findings reveal through different techniques (XPS, TGA, UV-vis, Raman, and TEM) an efficient n-doping of the SWCNT from the electron donor (metal)porphyrin through the efficient and strong amidinium-carboxylate connectivity.

Keyphrases

energy transfer
photodynamic therapy
electron transfer
resting state
metal organic framework
functional connectivity
white matter
quantum dots
water soluble
transition metal
genome wide
gene expression
molecular dynamics simulations
multiple sclerosis
oxide nanoparticles