Open-cage fullerenes as ligands for metals.

The remarkable structures of open-cage fullerenes with functionalization on the outer surface and an accessible inner void make them interesting ligands for reactions with metal complexes. The behaviors of open-cage fullerenes in reactions with various metal complexes are examined and compared to the corresponding reactions with intact fullerenes. The structural results from X-ray diffraction are emphasized. Open-cage fullerenes frequently undergo unanticipated structural changes such as carbon-carbon bond cleavage upon reactions with metal complexes. Much more remains to be learned about the possibility of inserting metal ions larger than Li + into the interior void of these open-cage fullerenes and about the effects of redox reactions on metal complexes of open-cage fullerenes.