Construction of in situ self-assembled FeWO 4 /g-C 3 N 4 nanosheet heterostructured Z-scheme photocatalysts for enhanced photocatalytic degradation of rhodamine B and tetracycline.

Although photocatalytic degradation is an ideal strategy for cleaning environmental pollution, it remains challenging to construct a highly efficient photocatalytic system by steering the charge flow in a precise manner. In this work, a novel, highly efficient, stable, and visible light active hybrid photocatalytic system consisting of FeWO 4 and g-C 3 N 4 nanosheets (CNNs) has been successfully prepared by an in situ self-assembly solvothermal approach. Several characterization techniques were employed to study the phase structures, morphologies, optical properties, surface composition and chemical state of the as-prepared samples. SEM and TEM results demonstrated that the FeWO 4 nanoparticles are uniformly dispersed on the surface of CNNs with a diameter of about 10-20 nm, which could provide maximum interfacial contact and a synergistic coupling effect between FeWO 4 and CNNs. XPS and FTIR results confirmed that there was strong electrostatic interaction between FeWO 4 and CNNs, suggesting the formation of heterojunctions between them. In addition, UV-DRS and PL spectroscopy revealed that the FeWO 4 /CNN composites exhibited increased visible light absorption and improved charge generation/separation efficiency. As a result, the photocatalytic activity of the FeWO 4 /CNNs was enhanced in comparison with pure FeWO 4 and CNNs for rhodamine B (RhB) and tetracycline (TC) degradation under natural sunlight irradiation. The photocatalytic efficiency of the optimal FeWO 4 /CNN composite (10 wt% FeWO 4 /CNNs) for the degradation of RhB (TC) was about 13.26 (4.95) and 86.2 (31.1) times higher than that of pure FeWO 4 and CNNs, respectively. Meanwhile, the 10 wt% FeWO 4 /CNN sample exhibits good photocatalytic stability in recycling experiments. The enhanced photocatalytic activity may be attributed to the formation of the Z-scheme system between FeWO 4 and CNNs, effectively prolonging the lifetime of the photoexcited electrons generated by CNNs and the photoexcited holes generated by FeWO 4 , which was subsequently confirmed by the active species trapping experiments and the calculation of relative band alignments. This work opens up a new feasible avenue to synthesize visible light active Z-scheme photocatalysts for application in energy production and environmental remediation.