Deposition of silver nanoparticles on nanoscroll-supported inorganic solid using incompletely rolled-up kaolinite.

Nanoscroll-supported platy particles were prepared by incomplete rolling-up of kaolinite layers; when the rolling-up of the kaolinite layer followed by its exfoliation incompletely proceeds, kaolinite nanoscrolls were found at the edge of kaolinite platy particles. To assess the support property of these nanoscroll-supported platy particles, when the deposition of Ag nanoparticles was conducted, these nanoparticles were present on the surface of platy particles and in the tubular interior of nanoscrolls at the edge of platy particles but absent on the surface of ordinal kaolinites, as revealed by X-ray diffraction, X-ray photoelectron spectroscopy, and transmission electron microscopy. These results indicated the successful formation and support property of nanoscroll-supported platy particles.