Thermally Programmable Dynamic Capillarity in Nanofluidic Channels Grafted with Smart Elastomeric Layers.

This work demonstrates thermally programmable dynamic capillarity in exclusively engineered nanochannels functionalized by grafted smart elastomeric layers onto their inner surfaces. Tunable control of the capillarity is observed over the temperature window of 25-31 °C, deciphering the possibility of a sevenfold alteration in the rate of capillary flow. A simple theory explains the confluence of viscous and capillary interactions as mediated by the non-trivial interplay of the substrate wettability, confinement-induced surface layering of molecules, and thermally activated modulation of surface tension, to bring out this intriguing effect. The technology is demonstrated to be completely reconfigurable over the intended spatial and temporal regimes, via selective grafting of the channel surface and preferential choice of the activation temperature. Such favorable features as opposed to more complex yet non-reconfigurable flow manipulation strategies previously reported are likely to open up new possibilities of highly precise controlled nanofluidic manipulation of temperature-sensitive biological samples and chemical species on-demand, for applications ranging from biomedical technologies to energy harvesting and water purification.